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- W1966917961 abstract "Base-induced cycloadditions of tosylmethyl isocyanide to a series of isothiocyanates have been investigated. Depending on the reaction conditions, thiazoles 5 and/or imidazoles 7 are obtained, with the thiazoles, in particular, being obtained with high regiospecificity. During the course of this work a high-yield ring transformation of 5-amino-1,3-thiazoles (5) to imidazole-5-thiols (7) was discovered, which has not been previously reported. A number of reactions of 7 are described." @default.
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- W1966917961 date "2010-09-02" @default.
- W1966917961 modified "2023-10-09" @default.
- W1966917961 title "Synthesis of thiazoles and imidazoles from isothiocyanates and tosylmethyl isocyanide. Base-induced ring transformation of 5-amino-1,3-thiazoles to imidazole-5-thiols" @default.
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- W1966917961 doi "https://doi.org/10.1002/recl.19821010102" @default.
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