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- W1966927402 abstract "N,N,N′,N′,N″,N″-hexaoctylnitrilotriacetamide (NTAamide(C8)) and N,N,N′,N′,N″,N″-hexabutylnitrilotriacetamide (NTAamide(C4)) were synthesized for selective solvent extraction of Th(IV) from U(VI) and lanthanides(III) (Lns(III)) and for coordination between Th(IV) and NTAamide, respectively. NTAamide(C8) exhibits excellent extraction power and selectivity toward Th(IV) over U(VI) and Lns(III) in a wide range of acidity from 0.1 to 10.0 M HNO3. Very high SFTh/M in the range between 2.5 × 102 and 10 × 103 was observed. Slope analysis shows that Th(IV), U(VI) and Lns(III) were all extracted as mono-solvated species at 3.0 M HNO3. The thermodynamic parameters describing the extraction of Th(IV) indicate that the process is endothermic and spontaneous at 298 K. The single-crystal X-ray diffraction observations also establish that 1:1 complex is formed between NTAamide and thorium nitrate, which are in good accordance with the solvent extraction results, and NTAamide is coordinated with Th(IV) in a tetradentate coordination mode." @default.
- W1966927402 created "2016-06-24" @default.
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- W1966927402 date "2014-12-01" @default.
- W1966927402 modified "2023-10-17" @default.
- W1966927402 title "High selective extraction for thorium(IV) with NTAamide in nitric acid solution: Synthesis, solvent extraction and structure studies" @default.
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- W1966927402 doi "https://doi.org/10.1016/j.seppur.2014.10.008" @default.
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