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- W1966935425 abstract "17O quadrupole double-resonance signals in natural abundance were observed from both oxygen nuclei of the short but asymmetric hydrogen bond in potassium hydrogen furan-3,4-dicarboxylate; both lineshapes show well-resolved 17O…1H dipolar structure, a theoretical analysis of which has shown that the two 17O quadrupole coupling constants are negative, with values of −6.525 MHz (η = 0.254)) for C17OH and −6.015 MHz (η = 0.797) for C17O…H. At both nuclei qzz (the maximum principal component of the electricfield gradient tensor) lies in the molecular plane, making an angle of 40 ± 10° with the OH direction for the former and 30 ± 15° for the latter, with qxx roughly perpendicular to the plane in both cases. The data are used to correlate the orientation and sign of the 17O electric field gradient tensor with the OH distance and the electronic structure at the oxygen atom in thirty hydrogen-bonded carbonyl compounds." @default.
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- W1966935425 date "1978-06-01" @default.
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- W1966935425 title "Nuclear magnetic resonance evidence for the occurrence of a low-temperature pseudo-cubic phase in the NbH system near NbH0.75" @default.
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- W1966935425 doi "https://doi.org/10.1016/0036-9748(78)90197-7" @default.
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