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- W1966960077 abstract "Reported is a novel, symmetry-based strategy for the synthesis of the zaragozic acids. Two enantioselective dihyroxylations are used to set the absolute stereochemistry of a C-2 symmetric intermediate. A sequence of a furan photo-oxidation followed by a diastereoselective dihydroxylation breaks the symmetry and sets two quaternary stereocenters. Finally, a group selective lactonization is used to protect one of two secondary hydroxyls. This accomplishes the critical end-differentiation of this intermediate. An approach to protecting group removal and oxidation is also presented." @default.
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- W1966960077 date "1998-11-01" @default.
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- W1966960077 title "A symmetry-based approach to zaragozic acid: Synthesis and end-differentiation of an advanced intermediate" @default.
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- W1966960077 doi "https://doi.org/10.1016/s0040-4039(98)01959-5" @default.
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