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- W1966960086 abstract "Eine umfangreiche Literaturrecherche zur Löslichkeit von nahe- bzw. überkritischen Fluiden (SCF) in Ionischen Flüssigkeiten (IL) zeigte, dass in der Regel die Gaslöslichkeit in den IL mit zunehmendem Druck und sinkender Temperatur zunimmt und dass unpolare, im Gegensatz zu polaren, SCF nur begrenzt in IL löslich sind. Diese Daten konnten mithilfe der Peng-Robinson-Zustandsgleichung unter Verwendung der Van-der-Waals-Mischungsregeln mit zwei binären Wechselwirkungsparametern sehr gut beschrieben werden. A review of existing experimental phase equilibrium data for systems of near- and/or supercritical fluids (SCF) and ionic liquids (IL) shows that usually the SCF solubility increases with increasing pressure and decreasing temperature. Additionally, polar SCF are better soluble in IL than nonpolar SCF. The experimental data could be correlated by means of the Peng-Robinson equation of state as well as the Van der Waals mixing rules. As a result, the experimental solubility can be calculated reasonably well using two binary interaction parameters." @default.
- W1966960086 created "2016-06-24" @default.
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- W1966960086 date "2014-04-07" @default.
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- W1966960086 title "Löslichkeit von überkritischen Fluiden in Ionischen Flüssigkeiten" @default.
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- W1966960086 doi "https://doi.org/10.1002/cite.201300161" @default.
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