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• W1966983402 abstract "Abstract Laboratory prepared and commercial poly(2‐2,2,2‐trifluoroethoxy‐2‐methyl)oxetane, P[3FOx] and poly(2‐2,2,2‐pentafluoropropoxy‐2‐methyl)oxetane, P[5FOx] polyols contain varying amounts of cyclics and low molar mass (LMW) constituents as byproducts of ring opening polymerization. Guided by phase diagrams determined by cloud point measurements, P[3FOx] diol separation is achieved. The impact of purification is explored via the preparation of P[3FOx] and P[5FOx] polyurethanes from cyclic/LMW‐free diols. Mechanical properties are improved because of higher polyurethane molecular weights. AFM revealed complex rugosity that is correlated with dynamic contact angles free from effects of water contamination." @default.
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• W1966983402 date "2012-04-19" @default.
• W1966983402 modified "2023-10-10" @default.
• W1966983402 title "Liquid-Liquid Extraction of 3FOx and 5FOx Polyoxetane Diols: Impact on Polyurethane Mechanical Properties, Surface Morphology, and Wetting Behavior" @default.
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• W1966983402 doi "https://doi.org/10.1002/macp.201200053" @default.
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