FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1966990907> ?p ?o ?g. }

• W1966990907 endingPage "4848" @default.
• W1966990907 startingPage "4839" @default.
• W1966990907 abstract "Tungsten(0)- and rhenium(I)-catalyzed reactions of acetylenic dienol silyl ethers based on the concept of geminal carbo-functionalization of alkynes are reported. Treatment of 3-siloxy-1,3-diene-7-ynes with catalytic amounts of [W(CO)6] or [ReCl(CO)5] under photoirradiation conditions gives synthetically useful bicyclo[3.3.0]octane derivatives in good yields. Extremely high catalytic activity is noted for the rhenium(I) complex. The reaction has been extended to substrates containing a nitrogen atom in their tethers. In this case, two kinds of synthetically useful heterocyclic compounds—the 2-azabicyclo[3.3.0]octane derivatives 9 and the monocyclic dihydropyrroles 10, with allenyl substituents—are obtained, and selective preparation of either product can be achieved through the use of an appropriate combination of the nitrogen substituent and the type of the rhenium(I) catalyst. The 2-azabicyclo[3.3.0]octane derivatives 9 are obtained selectively by carrying out treatment of NNs derivatives in the presence of [ReCl(CO)4(PPh3)], whereas the dihydropyrrole derivatives 10 are obtained by treatment of NMbs derivatives with [ReCl(CO)5]/AgSbF6. Finally, we have applied this geminal carbo-functionalization to one-carbon-elongated substrates containing NTs moieties in their tethers. Selective 5-exo cyclization is achieved in the presence of gold(I) or rhenium(I) catalysts, whereas 6-endo cyclization is observed on use of [W(CO)6]." @default.
• W1966990907 created "2016-06-24" @default.
• W1966990907 creator A5022969505 @default.
• W1966990907 creator A5043248930 @default.
• W1966990907 creator A5065697941 @default.
• W1966990907 creator A5074940978 @default.
• W1966990907 creator A5080780865 @default.
• W1966990907 creator A5090444211 @default.
• W1966990907 date "2011-03-21" @default.
• W1966990907 modified "2023-10-07" @default.
• W1966990907 title "Tungsten(0)- and Rhenium(I)-Catalyzed Tandem Cyclization of Acetylenic Dienol Silyl Ethers Based on Geminal Carbo-Functionalization of Alkynes" @default.
• W1966990907 cites W11839882 @default.
• W1966990907 cites W1964927227 @default.
• W1966990907 cites W1966776127 @default.
• W1966990907 cites W1967476703 @default.
• W1966990907 cites W1971816032 @default.
• W1966990907 cites W1981911740 @default.
• W1966990907 cites W1982524148 @default.
• W1966990907 cites W1984471932 @default.
• W1966990907 cites W1987542859 @default.
• W1966990907 cites W1990664188 @default.
• W1966990907 cites W1996000775 @default.
• W1966990907 cites W1998375603 @default.
• W1966990907 cites W2000911567 @default.
• W1966990907 cites W2003450014 @default.
• W1966990907 cites W2007038095 @default.
• W1966990907 cites W2012244682 @default.
• W1966990907 cites W2015970726 @default.
• W1966990907 cites W2025002140 @default.
• W1966990907 cites W2026434582 @default.
• W1966990907 cites W2030994018 @default.
• W1966990907 cites W2031644569 @default.
• W1966990907 cites W2032344698 @default.
• W1966990907 cites W2034588340 @default.
• W1966990907 cites W2034666141 @default.
• W1966990907 cites W2037584064 @default.
• W1966990907 cites W2037964091 @default.
• W1966990907 cites W2044673682 @default.
• W1966990907 cites W2049249446 @default.
• W1966990907 cites W2051681766 @default.
• W1966990907 cites W2053349400 @default.
• W1966990907 cites W2053470083 @default.
• W1966990907 cites W2054433914 @default.
• W1966990907 cites W2059754498 @default.
• W1966990907 cites W2062975057 @default.
• W1966990907 cites W2065700218 @default.
• W1966990907 cites W2075528588 @default.
• W1966990907 cites W2081196553 @default.
• W1966990907 cites W2085081277 @default.
• W1966990907 cites W2087973212 @default.
• W1966990907 cites W2096942566 @default.
• W1966990907 cites W2099674459 @default.
• W1966990907 cites W2100040845 @default.
• W1966990907 cites W2104403247 @default.
• W1966990907 cites W2107084891 @default.
• W1966990907 cites W2111226965 @default.
• W1966990907 cites W2113368796 @default.
• W1966990907 cites W2113396627 @default.
• W1966990907 cites W2114423946 @default.
• W1966990907 cites W2121970136 @default.
• W1966990907 cites W2123249521 @default.
• W1966990907 cites W2125806202 @default.
• W1966990907 cites W2128031355 @default.
• W1966990907 cites W2130543785 @default.
• W1966990907 cites W2132252779 @default.
• W1966990907 cites W2134554187 @default.
• W1966990907 cites W2137460597 @default.
• W1966990907 cites W2140687597 @default.
• W1966990907 cites W2145814579 @default.
• W1966990907 cites W2146040159 @default.
• W1966990907 cites W2152544727 @default.
• W1966990907 cites W2156846886 @default.
• W1966990907 cites W2160574842 @default.
• W1966990907 cites W2165157068 @default.
• W1966990907 cites W2167018421 @default.
• W1966990907 cites W2313223223 @default.
• W1966990907 cites W2317151712 @default.
• W1966990907 cites W2321436404 @default.
• W1966990907 cites W2322839115 @default.
• W1966990907 cites W2326176805 @default.
• W1966990907 cites W2510134875 @default.
• W1966990907 cites W2949112220 @default.
• W1966990907 cites W2949240157 @default.
• W1966990907 cites W2949680609 @default.
• W1966990907 cites W2949698852 @default.
• W1966990907 cites W2949790864 @default.
• W1966990907 cites W2950055802 @default.
• W1966990907 cites W2950640797 @default.
• W1966990907 cites W2950733543 @default.
• W1966990907 cites W2951248952 @default.
• W1966990907 cites W2951453856 @default.
• W1966990907 cites W2952235482 @default.
• W1966990907 cites W2952330213 @default.
• W1966990907 cites W2953083527 @default.
• W1966990907 cites W4211021418 @default.
• W1966990907 cites W4211044815 @default.
• W1966990907 cites W4234970529 @default.
• W1966990907 cites W4240411236 @default.

• next