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- W1966996959 abstract "Arsenic compounds, and especially organo‐arsenic derivatives, are highly toxic and many have been manufactured as chemical warfare agents. This study was designed to provide background information relevant to the potential application of aquathermolysis techniques for the detoxification of such potent military warfare agents. Six arsenic‐containing compounds with structural features which mimic known agents were studied in neutral superheated water: 4‐aminophenylarsine oxide, 4‐arsanilic acid, 4‐nitrophenylarsonic acid, 5, 10‐dihydro‐10‐ethylphenarsazine, tetraphenylarsonium chloride hydrate, and (3‐cyanopropyl)dimethyl(2‐phenethyl)arsonium bromide. Most of these compounds were moderately susceptible to hydrolysis for 1h at 300°C. o‐ and p‐Aminosubsituted arsenic compounds were more reactive than compounds with an electron‐withdrawing group substituent. Aromatic C—As bonds were more resistant to cleavage than aliphatic C—As bonds." @default.
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- W1966996959 date "1997-03-01" @default.
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- W1966996959 title "Aqueous high‐temperature chemistry of arsenic‐containing compounds in water at 300°C" @default.
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- W1966996959 doi "https://doi.org/10.1080/02772249709358439" @default.
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