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- W1967001113 abstract "A 1H NMR and rheological study of host-guest complexation interactions between three β-cyclodextrin and three adamantyl substituted poly(acrylate)s, and also between them and adamantan-1-carboxylate and native β-cyclodextrin, respectively, is reported. A close correllation between molecular level interactions and macroscopic characteristics of polymer networks in aqueous solution exists. It is found that intra- and intermolecular host-guest complexation between the host β-cyclodextrin and guest adamantyl substituents and the length of the aliphatic tether between them and the poly(acrylate) backbone have important roles. Dominantly, steric effects and competitive intra- and intermolecular host-guest complexation are found to control poly(acrylate) isomeric interstrand linkage in polymer network formation. The preparations of five new 3% randomly substituted poly(acrylate)s are reported. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1818–1825, 2010" @default.
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- W1967001113 date "2010-07-08" @default.
- W1967001113 modified "2023-09-26" @default.
- W1967001113 title "Steric effects and competitive intra- and intermolecular host-guest complexation between beta-cyclodextrin and adamantyl substituted poly(acrylate)s in water: A 1 H NMR, rheological and preparative study" @default.
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- W1967001113 doi "https://doi.org/10.1002/polb.22052" @default.
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