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- W1967022381 abstract "Abstract Die Silazanspaltung von Hexamethyldisilazan durch Diphenylphosphorchlorid führt je nach den Reaktionsbedingungen zu Trimethylchlorsilan und [(C 6 H 5 ) 2 P] 2 NH ( 1 ), [(C 6 H 5 ) 2 P] 3 N · HCl ( 4 ) und [(C 6 H 5 ) 2 P] 4 NCl ( 5 ). 1 setzt sich mit Diphenyl‐phosphorchlorid in Gegenwart von Triäthylamin zu (C 6 H 5 ) 2 PP(C 6 H 5 ) 2 NP(C 6 H 5 ) 2 ( 6 ) um, das auch durch Deprotonierung von 4 entsteht. 5 besitzt die Struktur eines Octaphenyltetraphosphornitridchlorids und ist besonders leicht aus (C 6 H 5 ) 2 PCl und (C 6 H 5 ) 2 PN[Si(CH 3 ) 3 ] 2 erhältlich." @default.
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- W1967022381 date "1967-02-01" @default.
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- W1967022381 title "Amino‐phosphane. VIII. Über ein Octaphenyltetraphosphornitridchlorid und ein Tetraphenyldiphosphin‐N‐diphenylphosphino‐imid" @default.
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- W1967022381 doi "https://doi.org/10.1002/zaac.19673490502" @default.
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