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• W1967029954 abstract "Ln(ClO4)3 and Ni(ClO4)2 self-assemble in the presence of amino acids (glycine, l-alanine or l-threonine) to form seven novel heptanuclear octahedral clusters {LnNi6} (Ln = La, Pr). X-ray structures are reported for Na[LaNi6(Gly)12](ClO4)4(H2O)11 (1), Na5[LaNi6(Gly)12](ClO4)8(H2O)10 (2), Na[PrNi6(Gly)12](ClO4)4(H2O)11 (3), [LaNi6(Gly)12][Ni(im)(H2O)5] · (ClO4)5(H2O)5 (4) and [LaNi6(Gly)12][Ni(NCS)3(H2O)3][Ni(NCS)2(H2O)4] · (ClO4)2(H2O)6 (5). l-Alanine and l-threonine were used as ligands to synthesize [LaNi6(Ala)12](ClO4)3 · (H2O)15 (6) and [LaNi6(Thr)12](ClO4)3 · (H2O)15 (7). In the [LnNi6(Gly)12]3+ ions, the Ln3+ ion is in the center of the octahedral cage formed by six nickel atoms and coordinates to 12 carboxylate oxygen atoms. Its coordination polyhedron may be best described as an icosahedron. Complexes 1, 3 and 4 exhibit ferromagnetic interactions." @default.
• W1967029954 created "2016-06-24" @default.
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• W1967029954 date "2004-09-01" @default.
• W1967029954 modified "2023-09-24" @default.
• W1967029954 title "Syntheses and characterizations of a series of heptanuclear octahedral polyhedra {LnNi6} with different amino acids as ligands in aqueous media" @default.
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• W1967029954 doi "https://doi.org/10.1016/j.poly.2004.07.012" @default.
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