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- W1967041714 abstract "Abstract A novel, water‐soluble, cationic PPV derivative poly{(2,5‐bis(3‐bromotrimethylammoniopropoxy)‐phenylene‐1,4‐divinylene)‐ alt ‐1,4‐(2,5‐bis(2‐(2‐hydroxyethoxy)ethoxy))phenylene vinylene} (BH‐PPV) has been synthesized by a Heck coupling reaction. Multilayered assemblies of the BH‐PPV and the sodium salt of hexa(sulfobutyl)fullerenes (C 60 ‐HS) were fabricated successfully by an alternate deposition technique. The multilayer structures were studied by UV/Vis spectroscopy, small angle X‐ray diffraction, and atomic force microscopy. The photoinduced charge transfer property of the self‐assembled multilayer film was also measured by a three‐electrode cell technique. A steady and rapid cathodic 5.5 μA cm −2 photocurrent response was measured as the irradiation of the multilayer film was switched on and off. Importantly, the response of on/off cycling is prompt and reproducible. A possible mechanism for the electron‐transfer process is proposed." @default.
- W1967041714 created "2016-06-24" @default.
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- W1967041714 date "2003-12-11" @default.
- W1967041714 modified "2023-10-17" @default.
- W1967041714 title "Photocurrent Generation in Multilayer Self-Assembly Films Fabricated from Water-Soluble Poly(phenylene vinylene)" @default.
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