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- W1967048683 abstract "Experiments are reported on the oxidative hydrothermal destruction of chlorinated organics in a cor rosion-resistant titanium reactor. Oxidation reaction conditions were 250−500 °C near 650 bar and reaction times of 30−100 s in a continuous-flow reactor. Trichloroacetic acid, trichloroethylene, and 1,1,1-trichloroethane behaved similarly. The organic concentration was ∼1.5 wt %; hydrogen peroxide was the oxidizer; sodium bicarbonate was added to achieve neutral pH. Hydrolysis occurs at low temper ature, producing chloride ion and secondary organics. Carbon dioxide is the sole carbon product at 500 °C. Sodium nitrate and sodium nitrite were also found to be effective oxidizers. Corrosion of the titanium was found to be slight (<0.038 mm/yr). The reaction mixture is likely not a single phase at these conditions. The destruction efficiency for trichloroethylene was estimated as 99.96% at 450 °C and 60 s, with <0.02% conversion to volatile chlorinated organic byproducts." @default.
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- W1967048683 date "1996-08-01" @default.
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- W1967048683 title "Hydrothermal Processing of Chlorinated Hydrocarbons in a Titanium Reactor" @default.
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- W1967048683 doi "https://doi.org/10.1021/es960041o" @default.
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