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- W1967055541 abstract "Both stationary and laser flash photolysis were used to study the photochemistry of IrCl 6 2− in alcohol solutions. The primary photochemical photolysis process at 308 nm was demonstrated to involve electron transfer from the solvent to the excited complex. When the photolysis was performed at 248 nm, the photodissociation of the excited complex, with the elimination of a chlorine atom from the coordination sphere of iridium, was accompanied by electron transfer. At room temperature, the rate constants of the reaction between the primary alcohol radicals and the IrCl 6 2− complex were determined to be (3.2±0.1) × 10 9 M −1 s −1 for hydroxymethyl and (2.3±0.1) × 10 9 M −1 s −1 for α-hydroxyethyl radicals. The dark reactions of the IrCl 6 2− complex arising from photolysis are discussed." @default.
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- W1967055541 date "1995-08-01" @default.
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- W1967055541 title "Photochemistry of IrCl62− complex in alcohol solutions" @default.
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