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- W1967156932 abstract "The orange complex Cp*Fe(C5H5BMe) (1a) was synthesized from [Cp*Fe(NCMe)3]PF6 and Li(C5H5BMe) in 91% yield. Electrophilic stacking reactions with metalloelectrophiles gave the triple-decker salts [(μ-C5H5BMe)(FeCp*)2]PF6 (4), [(μ-C5H5BMe)(FeCp*)(RuCp*)]CF3SO3 (5), and [(μ-C5H5BMe)(FeCp*)(MCp*)](CF3SO3)2 with M = Rh (for 6) and M = Ir (for 7). Electrophilic stacking of Rh(C5H5BMe)(COD) (8) with [(COD)Rh(MeNO2)x]CF3SO3 gave [(μ-C5H5BMe){Rh(COD)}2CF3SO3 (10). The structures of the two triple-decker complexes 4 and 10 were determined by X-ray diffraction. Boratabenzene transfer reactions were found for the heterobimetallic salts 5−7." @default.
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- W1967156932 date "1996-11-26" @default.
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- W1967156932 title "Triple-Decker Complexes. 12.<sup>1</sup> Triple-Decker Complexes with Bridging Boratabenzene Ligands. Syntheses, Structures of [(μ-C<sub>5</sub>H<sub>5</sub>BMe)(FeCp*)<sub>2</sub>]PF<sub>6</sub> and of [(μ-C<sub>5</sub>H<sub>5</sub>BMe){Rh(COD)}<sub>2</sub>]CF<sub>3</sub>SO<sub>3</sub>, and Boratabenzene Transfer Reactions" @default.
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- W1967156932 doi "https://doi.org/10.1021/om960536m" @default.
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