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- W1967186720 abstract "The use of vibration frequency shifts due to isotopic substitution at the bridge position in the molecules BF3, SiF4 and NO2 is discussed, using frequency data in the literature for the 10B, 11B, 28Si, 30Si, 14N and 15N species. The agreement between force fields calculated respectively from the shifts and from the Coriolis coefficients is good for BF3 but not so good for SiF4. The accuracy of a first order perturbation treatment for frequency shifts is tested and found wanting for BF3 and CF4. In NO2 existing data on anharmonicity contents and harmonic frequencies cast some doubt on the utility of Dennison's rule as a means for estimating anharmonicity; however the isotopic shift on v2 continues to be valuable in determining the normal coordinates." @default.
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- W1967186720 date "1966-02-01" @default.
- W1967186720 modified "2023-09-27" @default.
- W1967186720 title "Accurate force constants from heavy isotopic substitution—II. BF3, SiF4 and NO2" @default.
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- W1967186720 doi "https://doi.org/10.1016/0371-1951(66)80237-0" @default.
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