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• W1967198067 abstract "Abstract Segmental charge distributions of Cytochrome c ions in the transition from solution to gas phase are studied by native electron capture dissociation (NECD). The data suggest that the solution charge distribution of native Cytochrome c is partially preserved during the electrospray ionization process. Segments with charge values different from those in solution correspond to protein regions that are the first to unfold on transfer into the gas phase, consistent with an increased gas phase basicity of, and facile proton transfer to, the newly exposed sites. Changes in the charge distribution at elevated temperatures indicate further unfolding, as well as proton transfer as a result of the increased electrostatic interactions in a gas phase environment." @default.
• W1967198067 created "2016-06-24" @default.
• W1967198067 creator A5090748372 @default.
• W1967198067 date "2006-07-01" @default.
• W1967198067 modified "2023-09-27" @default.
• W1967198067 title "Segmental charge distributions of Cytochrome c on transfer into the gas phase" @default.
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• W1967198067 doi "https://doi.org/10.1016/j.ijms.2006.04.004" @default.
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