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- W1967268718 abstract "The crystal structures of novel products from the insertion of various diazoalkanes into the iron−phosphorus bond in FeCl2L2 (L = phosphine) complexes are presented. Specifically, ethyl diazoacetate and diphenyldiazomethane reacted with FeCl2(PMe2Ph)2 to afford FeCl2[N(PMe2Ph)NC(H)CO2Et]2 (1) and FeCl2[N(PMe2Ph)NCPh2] (2). Interestingly, ethyl diazoacetate inserted into both iron phosphine bonds of FeCl2(dippe)2 to afford the seven-membered metallacycle (3)." @default.
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- W1967268718 date "2001-01-06" @default.
- W1967268718 modified "2023-10-12" @default.
- W1967268718 title "Reaction of Diazoalkanes with Iron Phosphine Complexes Affords Novel Phosphazine Complexes" @default.
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- W1967268718 doi "https://doi.org/10.1021/om000586y" @default.
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