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• W1967305028 endingPage "9471" @default.
• W1967305028 startingPage "9465" @default.
• W1967305028 abstract "The dispersed fluorescence of the à 2A1–X̃ 2E system of CH3O and 13CH3O in a supersonic jet was recorded after excitation of various vibrational levels of the à state. Analysis of the spectra yielded ν2″ = 1412, ν3″ = 1047, ν5″ = 1494, and ν6″ = 653 cm−1 for the X̃ state of 12CH3O, and ν2″ = 1408, ν3″ = 1027, ν5″ = 1488, and ν6″ = 649 cm−1 for 13CH3O. The least-squares fitting of the observed 300–306 lines (with spin–orbit splitting removed) yielded ωe=1057±3 cm−1 and ωexe=7.0±0.7 cm−1 for ν3″ of 12CH3O. Several tentative assignments were also made on the basis of the improved fluorescence spectra. The Fermi-resonant levels 1289 and 1319 cm−1 above v=0 of the à state were also reassigned; the former is better represented as v2′ = 1, whereas the latter is represented as v3′ = 2." @default.
• W1967305028 created "2016-06-24" @default.
• W1967305028 creator A5002073160 @default.
• W1967305028 creator A5015444281 @default.
• W1967305028 creator A5037198749 @default.
• W1967305028 date "1993-12-15" @default.
• W1967305028 modified "2023-10-14" @default.
• W1967305028 title "Vibronic analysis of the <i>A</i>̃→<i>X</i>̃ laser‐induced fluorescence of jet‐cooled methoxy (CH₃O) radical" @default.
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• W1967305028 doi "https://doi.org/10.1063/1.465481" @default.
• W1967305028 hasPublicationYear "1993" @default.
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