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• W1967309189 abstract "An optically active semi‐fluorinated alkanol, (S)‐1‐methyl‐2‐(2,2,3,3,3‐pentafluoropropyloxy)ethanol, was prepared by the treatment of 2,2,3,3,3‐pentafluoropropanol with (S)‐propylene oxide under basic conditions. This alkanol was used as a chiral building block for the synthesis of a series of novel chiral materials, the (R)‐4‐[1‐methyl‐2‐(2,2,3,3,3‐pentafluoropropyloxy)ethyloxycarbonyl]phenyl 4′‐alkyloxybiphenyl‐4‐carboxylates, MPFPECPmBC (m = 8–12), that have a semi‐fluorinated alkane positioned at the chiral tail. It was found that all the materials possess enantiotopic SmA*, ferroelectric SmC* and antiferroelectric phases. The basic electro‐optical properties of the chiral materials in the SmC* and phases were measured. The results show that the maximum P s values are in the range 69–92 nC cm−2 and the maximum apparent title angles are in a range of 24°–33°." @default.
• W1967309189 created "2016-06-24" @default.
• W1967309189 creator A5046601848 @default.
• W1967309189 creator A5056183327 @default.
• W1967309189 date "2005-09-01" @default.
• W1967309189 modified "2023-10-18" @default.
• W1967309189 title "Antiferroelectric liquid crystals having a semi‐fluorinated alkane positioned at the chiral tail" @default.
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• W1967309189 doi "https://doi.org/10.1080/02678290500291632" @default.
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