Matches in SemOpenAlex for { <https://semopenalex.org/work/W1967355118> ?p ?o ?g. }
- W1967355118 endingPage "626" @default.
- W1967355118 startingPage "621" @default.
- W1967355118 abstract "Ethylene was formed from 1-aminocyclopropane-1-carboxylic acid (ACC) by a wholly defined system containing linoleic acid hydroperoxide (LOOH), Mn2+ and pyridoxal 5′-phosphate (PP) at pH 8.0. Under these conditions, neither oxygen nor lipoxygenase was required for ethylene production. Each component of the reaction mixture has been implicated as a cofactor required for aerobic in vitro conversion of ACC to ethylene by various plant preparations. Inhibition of ethylene formation by the α-tocopherol analogue, 2,2,5,7,8-pentamethyl-6-hydroxychroman, implies that free radicals are involved in the reaction. Peroxy radicals of LOOH were demonstrated to form in parallel with ethylene. Although PP was required for ethylene formation, peroxy radicals formed equally well with or without PP. This result implies that either a PP-ACC Schiff base reacts with peroxy radicals, or that peroxy radicals act through a PP-Mnn+ complex. Since the known stereochemistry argued against the former possibility [Pirrung, M. (1986) Biochemistry 25, 114], the latter is suggested. A possible mechanism is proposed involving oxidation of ACC by a PP-Mn4+ LOO− complex formed via sequential oxidation of Mn2+ by LOOH and peroxy radicals derived from LOOH." @default.
- W1967355118 created "2016-06-24" @default.
- W1967355118 creator A5031973604 @default.
- W1967355118 creator A5038360218 @default.
- W1967355118 date "1987-01-01" @default.
- W1967355118 modified "2023-09-26" @default.
- W1967355118 title "Lipid hydroperoxides in the conversion of 1-aminocyclopropane-1-carboxylic acid to ethylene" @default.
- W1967355118 cites W1514324130 @default.
- W1967355118 cites W1535328385 @default.
- W1967355118 cites W1965846879 @default.
- W1967355118 cites W1969897706 @default.
- W1967355118 cites W1974121205 @default.
- W1967355118 cites W1975112187 @default.
- W1967355118 cites W1987055266 @default.
- W1967355118 cites W1990080654 @default.
- W1967355118 cites W1990294392 @default.
- W1967355118 cites W1995327391 @default.
- W1967355118 cites W1995584153 @default.
- W1967355118 cites W2008137909 @default.
- W1967355118 cites W2009099136 @default.
- W1967355118 cites W2009125845 @default.
- W1967355118 cites W2011491690 @default.
- W1967355118 cites W2015063600 @default.
- W1967355118 cites W2015768512 @default.
- W1967355118 cites W2034950504 @default.
- W1967355118 cites W2035488328 @default.
- W1967355118 cites W2047908599 @default.
- W1967355118 cites W2057238216 @default.
- W1967355118 cites W2061273382 @default.
- W1967355118 cites W2062443989 @default.
- W1967355118 cites W2068238508 @default.
- W1967355118 cites W2082505440 @default.
- W1967355118 cites W2082871670 @default.
- W1967355118 cites W2085705518 @default.
- W1967355118 cites W2086722177 @default.
- W1967355118 cites W2088003029 @default.
- W1967355118 cites W2092079897 @default.
- W1967355118 cites W2095245534 @default.
- W1967355118 cites W2099862214 @default.
- W1967355118 cites W2102450440 @default.
- W1967355118 cites W2135277059 @default.
- W1967355118 cites W2174475512 @default.
- W1967355118 cites W2242509326 @default.
- W1967355118 cites W2315632267 @default.
- W1967355118 cites W2333104353 @default.
- W1967355118 cites W2342925464 @default.
- W1967355118 doi "https://doi.org/10.1016/s0031-9422(00)84753-6" @default.
- W1967355118 hasPublicationYear "1987" @default.
- W1967355118 type Work @default.
- W1967355118 sameAs 1967355118 @default.
- W1967355118 citedByCount "28" @default.
- W1967355118 countsByYear W19673551182012 @default.
- W1967355118 countsByYear W19673551182014 @default.
- W1967355118 countsByYear W19673551182015 @default.
- W1967355118 countsByYear W19673551182017 @default.
- W1967355118 crossrefType "journal-article" @default.
- W1967355118 hasAuthorship W1967355118A5031973604 @default.
- W1967355118 hasAuthorship W1967355118A5038360218 @default.
- W1967355118 hasConcept C139066938 @default.
- W1967355118 hasConcept C155647269 @default.
- W1967355118 hasConcept C161790260 @default.
- W1967355118 hasConcept C178790620 @default.
- W1967355118 hasConcept C185592680 @default.
- W1967355118 hasConcept C2778597550 @default.
- W1967355118 hasConcept C2780068497 @default.
- W1967355118 hasConcept C2780809830 @default.
- W1967355118 hasConcept C540031477 @default.
- W1967355118 hasConcept C543025807 @default.
- W1967355118 hasConcept C71240020 @default.
- W1967355118 hasConcept C75473681 @default.
- W1967355118 hasConceptScore W1967355118C139066938 @default.
- W1967355118 hasConceptScore W1967355118C155647269 @default.
- W1967355118 hasConceptScore W1967355118C161790260 @default.
- W1967355118 hasConceptScore W1967355118C178790620 @default.
- W1967355118 hasConceptScore W1967355118C185592680 @default.
- W1967355118 hasConceptScore W1967355118C2778597550 @default.
- W1967355118 hasConceptScore W1967355118C2780068497 @default.
- W1967355118 hasConceptScore W1967355118C2780809830 @default.
- W1967355118 hasConceptScore W1967355118C540031477 @default.
- W1967355118 hasConceptScore W1967355118C543025807 @default.
- W1967355118 hasConceptScore W1967355118C71240020 @default.
- W1967355118 hasConceptScore W1967355118C75473681 @default.
- W1967355118 hasIssue "3" @default.
- W1967355118 hasLocation W19673551181 @default.
- W1967355118 hasOpenAccess W1967355118 @default.
- W1967355118 hasPrimaryLocation W19673551181 @default.
- W1967355118 hasRelatedWork W1969404129 @default.
- W1967355118 hasRelatedWork W2061908415 @default.
- W1967355118 hasRelatedWork W2066055199 @default.
- W1967355118 hasRelatedWork W2074835548 @default.
- W1967355118 hasRelatedWork W2084186860 @default.
- W1967355118 hasRelatedWork W2148244385 @default.
- W1967355118 hasRelatedWork W2810510838 @default.
- W1967355118 hasRelatedWork W2949302172 @default.
- W1967355118 hasRelatedWork W2949777230 @default.
- W1967355118 hasRelatedWork W2989710099 @default.
- W1967355118 hasVolume "26" @default.
- W1967355118 isParatext "false" @default.