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- W1967390410 abstract "The synthesis, characterisation, X-ray crystal structure and electrochemical properties of a new redox-active labelling reagent, N-(ferrocenyl)iodoacetamide (Fc-IAA), are reported. This compound exhibits a reversible ferrocenium/ferrocene couple at ca. +0.345 V vs. SCE at a sweep rate of 100 mV s−1 in CH3CN at 298 K, and two irreversible reduction waves at ca. −1.324 and −2.048 V, attributable to the reduction of the iodoacetamide group. Since the iodoacetamide moiety can react specifically with the sulfhydryl group, Fc-IAA has been coupled to various biomolecules including a sulfhydryl-modified oligonucleotide, cysteine, glutathione and sulfhydryl-modified bovine serum albumin. The electrochemical properties of the bioconjugates have also been investigated." @default.
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- W1967390410 date "2002-03-12" @default.
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- W1967390410 title "Specific labelling of sulfhydryl-containing biomolecules with redox-active N-(ferrocenyl)iodoacetamide" @default.
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- W1967390410 doi "https://doi.org/10.1039/b111529d" @default.
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