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- W1967404662 abstract "Treatment of homopropargylic alcohol and its derivatives or propargylic alcohols with tetraallylmanganate or triallylmanganate provided monoallylated products in good yields with high regio- and stereoselectivities. The intermediary alkenylmanganese compounds were trapped by various electrophiles. The reaction was clearly oxygen-assisted since 6-dodecyne was completely recovered unchanged. Diallylation products were obtained in the presence of air. Allylmagnesation and diallylation of these acetylenic compounds catalyzed by manganese salts are also disclosed." @default.
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- W1967404662 date "1997-04-01" @default.
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- W1967404662 title "Allylmanganation and diallylation of acetylenic compounds" @default.
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- W1967404662 doi "https://doi.org/10.1016/s0040-4020(97)00201-9" @default.
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