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• W1967432153 abstract "To assign the observed vibrationsl modes in the resonance Raman spectrum of the retinylidene chromophore of rhodopsin, we have studied chemically modified retinals. The series of analogs investigated are the n-butyl retinals substituted at C9 and C13. The results obtained for the 11-cis isomer have clearly assigned the CCH3 vibrational frequencies observed in the spectrum of the retinylidene chromophore. The data show that the C(9)CH3 stretching vibration can be assigned to the vibrational mode observed in the 1017 cm−1 region, and the vibration detected at 997 cm−1 can be assigned to the C(13CH3 vibration. The C(5)CH3 stretching mode does not contribute to the vibrations observed in this region. The splitting in the C(n)CH3 (n = 9, 13) vibration is characteristic of the 11-cis conformation. The results on the modified retinals do not support the hypothesis that the splitting arises from equilibrium mixtures of 11-cis, 12-s-cis and 11-cis, 12-s-trans in solution. Thus, this splitting cannot be used to determine whether the chromophore in rhodopsin is in a 12-s-cis or 12-s-trans conformation. However, our results demonstrate that there are other vibrational modes in the spectra which are sensitive to this conformational equilibrium and we use the presence of a strong ~ 1271 cm−1 mode in bovine and squid rhodopsin spectra as an indication that the chromophore in these pigments is 11-cis, 12-s-trans." @default.
• W1967432153 created "2016-06-24" @default.
• W1967432153 creator A5024264517 @default.
• W1967432153 creator A5067367640 @default.
• W1967432153 date "1978-03-01" @default.
• W1967432153 modified "2023-10-16" @default.
• W1967432153 title "Resonance Raman spectroscopy of chemically modified retinals: Assigning the carbon-methyl vibrations in the resonance Raman spectrum of rhodopsin" @default.
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• W1967432153 doi "https://doi.org/10.1016/0022-2836(78)90203-6" @default.
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