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- W1967432810 abstract "Abstract An investigation has been carried out to study the limited miscibility of methanol and gasoline blends over the temperature range −20 to 20°C. Two liquid phases in equilibrium were analysed by mass spectrometric methods and their composition reported, in addition to the methanol content, in terms of six principal classes of hydrocarbons. Liquid—liquid equilibrium was predicted using the UNIFAC group contribution model. In liquidliquid equilibrium calculations, gasoline was represented by a set of model compounds. The number of the different groups that comprise each model molecule was determined using the result of a distillation analysis and the paraffin—naphthene—aromatic composition. Estimation of conjugate phase composition using the UNIFAC model is reasonable at temperatures above 0°C. To describe correctly the limited miscibility of methanol+gasoline blends over the whole temperature range studied, we found that ‘specific’ UNIFAC interaction parameters were necessary." @default.
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- W1967432810 date "1986-10-01" @default.
- W1967432810 modified "2023-10-06" @default.
- W1967432810 title "Liquid—liquid equilibrium in methanol + gasoline blends" @default.
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- W1967432810 doi "https://doi.org/10.1016/0378-3812(86)87004-2" @default.
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