FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1967437536> ?p ?o ?g. }

• W1967437536 endingPage "14697" @default.
• W1967437536 startingPage "14688" @default.
• W1967437536 abstract "1,3-Disubstituted imidazolium ionic liquids have been the subject of numerous theoretical and experimental studies due to their low viscosity—often the very lowest for any given cation/anion family. One of the mysteries in the imidazolium family of salts is the sharp increase in viscosity that is observed on methylating at the C2 position in the ring. In the nonmethylated case, the C2 proton is observed to be distinctly acidic and, where this is undesirable, substitution of the C2 position removes the problem, but produces an unexpected increase in viscosity. Methylation at other positions on the ring does not produce such a significant effect. In this study, two possible structural or energetic sources of the increased viscosity were investigated: (1) ion association, as probed by the Walden rule, and (2) differences in the potential energy surface profiles that favor ionic transport in the non C2-methylated imidazolium ionic liquids. The second hypothesis was investigated using high-level ab initio theory. The higher viscosity of C2-methylated imidazolium ionic liquids is shown to be a result of high potential energy barriers (significantly above the available thermal energy) between the energetically preferred conformations on the potential energy surface, thus restricting movement of ions in the liquid state to only small oscillations and inhibiting the overall ion transport." @default.
• W1967437536 created "2016-06-24" @default.
• W1967437536 creator A5004042298 @default.
• W1967437536 creator A5017109393 @default.
• W1967437536 creator A5019648567 @default.
• W1967437536 creator A5028309742 @default.
• W1967437536 creator A5056358014 @default.
• W1967437536 creator A5066884482 @default.
• W1967437536 creator A5085886271 @default.
• W1967437536 date "2011-11-14" @default.
• W1967437536 modified "2023-09-27" @default.
• W1967437536 title "Understanding the Effect of the C2 Proton in Promoting Low Viscosities and High Conductivities in Imidazolium-Based Ionic Liquids: Part I. Weakly Coordinating Anions" @default.
• W1967437536 cites W1965200916 @default.
• W1967437536 cites W1970257706 @default.
• W1967437536 cites W1976496891 @default.
• W1967437536 cites W1979125578 @default.
• W1967437536 cites W1992718099 @default.
• W1967437536 cites W1996573551 @default.
• W1967437536 cites W1996792541 @default.
• W1967437536 cites W2001187016 @default.
• W1967437536 cites W2001192581 @default.
• W1967437536 cites W2002012954 @default.
• W1967437536 cites W2004746721 @default.
• W1967437536 cites W2008937980 @default.
• W1967437536 cites W2016921865 @default.
• W1967437536 cites W2022183351 @default.
• W1967437536 cites W2023481147 @default.
• W1967437536 cites W2023828347 @default.
• W1967437536 cites W2032720602 @default.
• W1967437536 cites W2039639599 @default.
• W1967437536 cites W2045386163 @default.
• W1967437536 cites W2045706649 @default.
• W1967437536 cites W2046592431 @default.
• W1967437536 cites W2047850266 @default.
• W1967437536 cites W2048164835 @default.
• W1967437536 cites W2048421180 @default.
• W1967437536 cites W2049692911 @default.
• W1967437536 cites W2054473073 @default.
• W1967437536 cites W2059289107 @default.
• W1967437536 cites W2060151241 @default.
• W1967437536 cites W2061253553 @default.
• W1967437536 cites W2069507544 @default.
• W1967437536 cites W2072260070 @default.
• W1967437536 cites W2073054991 @default.
• W1967437536 cites W2073206670 @default.
• W1967437536 cites W2078028298 @default.
• W1967437536 cites W2081874690 @default.
• W1967437536 cites W2086032643 @default.
• W1967437536 cites W2097175735 @default.
• W1967437536 cites W2099062902 @default.
• W1967437536 cites W2114479908 @default.
• W1967437536 cites W2148941593 @default.
• W1967437536 cites W286815202 @default.
• W1967437536 cites W3023435578 @default.
• W1967437536 cites W4247361083 @default.
• W1967437536 cites W4319287624 @default.
• W1967437536 doi "https://doi.org/10.1021/jp208573y" @default.
• W1967437536 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22023104" @default.
• W1967437536 hasPublicationYear "2011" @default.
• W1967437536 type Work @default.
• W1967437536 sameAs 1967437536 @default.
• W1967437536 citedByCount "100" @default.
• W1967437536 countsByYear W19674375362012 @default.
• W1967437536 countsByYear W19674375362013 @default.
• W1967437536 countsByYear W19674375362014 @default.
• W1967437536 countsByYear W19674375362015 @default.
• W1967437536 countsByYear W19674375362016 @default.
• W1967437536 countsByYear W19674375362017 @default.
• W1967437536 countsByYear W19674375362018 @default.
• W1967437536 countsByYear W19674375362019 @default.
• W1967437536 countsByYear W19674375362020 @default.
• W1967437536 countsByYear W19674375362021 @default.
• W1967437536 countsByYear W19674375362022 @default.
• W1967437536 countsByYear W19674375362023 @default.
• W1967437536 crossrefType "journal-article" @default.
• W1967437536 hasAuthorship W1967437536A5004042298 @default.
• W1967437536 hasAuthorship W1967437536A5017109393 @default.
• W1967437536 hasAuthorship W1967437536A5019648567 @default.
• W1967437536 hasAuthorship W1967437536A5028309742 @default.
• W1967437536 hasAuthorship W1967437536A5056358014 @default.
• W1967437536 hasAuthorship W1967437536A5066884482 @default.
• W1967437536 hasAuthorship W1967437536A5085886271 @default.
• W1967437536 hasConcept C121332964 @default.
• W1967437536 hasConcept C125277925 @default.
• W1967437536 hasConcept C127172972 @default.
• W1967437536 hasConcept C145148216 @default.
• W1967437536 hasConcept C147597530 @default.
• W1967437536 hasConcept C154881586 @default.
• W1967437536 hasConcept C159467904 @default.
• W1967437536 hasConcept C161790260 @default.
• W1967437536 hasConcept C178790620 @default.
• W1967437536 hasConcept C185592680 @default.
• W1967437536 hasConcept C2182769 @default.
• W1967437536 hasConcept C2781442258 @default.
• W1967437536 hasConcept C54516573 @default.
• W1967437536 hasConcept C62520636 @default.
• W1967437536 hasConcept C97355855 @default.
• W1967437536 hasConceptScore W1967437536C121332964 @default.

• next