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• W1967454830 endingPage "2372" @default.
• W1967454830 startingPage "2367" @default.
• W1967454830 abstract "Effects of electron irradiation on a methylthiolate (CH3S) self-assembled monolayer on Au(111) have been studied by using scanning tunneling microscope (STM), Auger electron spectroscopy (AES), low-energy electron diffraction, and thermal-desorption spectroscopy (TDS). AES results indicated that irradiation of the CH3S/Au(111) surface by an electron beam induces electron-stimulated desorption (ESD), in which mainly the methyl moiety desorbs via S−C bond cleavage, leaving a sulfur atom on the surface. From a quantitative analysis of TD spectra, the cross section of the ESD is estimated to be 2.8 × 10-17 cm2 for 100-eV electrons. Two-dimensional arrangements of the methylthiolate and the sulfur species under the ESD process have been investigated with STM. The STM observations indicated that the sulfur adatoms form 2D islands that grow in size with the progress of the ESD process, while unaffected methylthiolates are distributed between the sulfur islands. After the completion of the ESD, the Au(111) surface is covered with small patches (≲100 Å) of sulfur domains." @default.
• W1967454830 created "2016-06-24" @default.
• W1967454830 creator A5033025107 @default.
• W1967454830 creator A5041562042 @default.
• W1967454830 date "1998-03-01" @default.
• W1967454830 modified "2023-09-30" @default.
• W1967454830 title "Effects of Electron Irradiation on Methylthiolate Monolayer on Au(111): Electron-Stimulated Desorption" @default.
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• W1967454830 doi "https://doi.org/10.1021/jp972170c" @default.
• W1967454830 hasPublicationYear "1998" @default.
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