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- W1967552574 abstract "The title compound, Cu2(2-NO2C6H4COO)4(DMSO)2, crystallizes in the monoclinic space group P21/n, with a=10.621(4), b=10.480(3), c=17.5 67(10) Å, β=96.15(8)°. Single crystal X-ray data of 2534 independent reflections converged to a conventional R factor of 0.043. The complex has dimeric structure (copper acetate type), in which two copper(II) atoms are separated by 2.702(1) Å and bridged by four bidentate carboxylate groups with CuO (average) distance of 1.984(3) Å. The apical CuO bond to the DMSO molecule is 2.167(3) Å. There is a centre of symmetry at the middle of the CuCu bond. Fitting of the modified Bleaney-Bowers equation to the magnetic susceptibility data yielded a singlet-triplet separation of 2J = −334 cm−1. The main properties of IR, EPR and electronic spectra at room temperature and the magnetic properties down to 4.2 K are reported." @default.
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- W1967552574 date "1989-08-01" @default.
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- W1967552574 title "Spectroscopic, magnetic and structural characterization of bis(dimethyl sulfoxide)tetrakis(μ-2-nitrobenzoato-O,O′)dicopper(II)" @default.
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- W1967552574 doi "https://doi.org/10.1016/s0020-1693(00)83117-5" @default.
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