Matches in SemOpenAlex for { <https://semopenalex.org/work/W1967564564> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W1967564564 endingPage "29" @default.
- W1967564564 startingPage "23" @default.
- W1967564564 abstract "Methods of voltammetry and polarography have been applied to study electrochemical behavior of ultrafine copper particles with Z -average diameter ∼120 nm in aqueous electrolytic media on mercury electrodes. Particles have been preliminarily stabilized by controllable passivation at low partial pressures of oxygen what resulted in formation of superficial oxide shell with certain composition and structure. It has been found that special electrochemical behavior of the particles in aqueous media is caused by the size effects as well as by the processes (partial dissolution, complexation) occurring at the “particle/solution” interface. Electroreduction of the dispersions takes place at about –0.8 V (Ag/AgCl/KCl sat.). The mechanism of electroreduction includes an adsorption stage due to electric charge which the particles bear in the electrolyte. The particle adsorption on the electrode has been shown by differential capacity measurements, the surface charge in different electrolytes was estimated by means of potentiometric titration of the dispersions. The sign of the charge and the probable electroactive species formed by partial dissolution of CuO and Cu 2 O in the electrolytic medium have been considered on basis of equilibria at the copper particle/dispersion interface." @default.
- W1967564564 created "2016-06-24" @default.
- W1967564564 creator A5018869923 @default.
- W1967564564 creator A5023481360 @default.
- W1967564564 date "2009-04-01" @default.
- W1967564564 modified "2023-09-25" @default.
- W1967564564 title "Electrochemical behavior of copper metal core/oxide shell ultra-fine particles on mercury electrodes in aqueous dispersions" @default.
- W1967564564 cites W1965184792 @default.
- W1967564564 cites W1978215404 @default.
- W1967564564 cites W1978801799 @default.
- W1967564564 cites W2012359312 @default.
- W1967564564 cites W2014073966 @default.
- W1967564564 cites W2018098301 @default.
- W1967564564 cites W2022690372 @default.
- W1967564564 cites W2023110924 @default.
- W1967564564 cites W2037550179 @default.
- W1967564564 cites W2048755825 @default.
- W1967564564 cites W2051996757 @default.
- W1967564564 cites W2059149927 @default.
- W1967564564 cites W2074249275 @default.
- W1967564564 cites W2083611443 @default.
- W1967564564 cites W2123637015 @default.
- W1967564564 cites W2125634486 @default.
- W1967564564 cites W2149709030 @default.
- W1967564564 cites W2159512772 @default.
- W1967564564 cites W2318050077 @default.
- W1967564564 doi "https://doi.org/10.1016/j.jelechem.2009.01.009" @default.
- W1967564564 hasPublicationYear "2009" @default.
- W1967564564 type Work @default.
- W1967564564 sameAs 1967564564 @default.
- W1967564564 citedByCount "7" @default.
- W1967564564 countsByYear W19675645642012 @default.
- W1967564564 countsByYear W19675645642014 @default.
- W1967564564 countsByYear W19675645642017 @default.
- W1967564564 countsByYear W19675645642018 @default.
- W1967564564 crossrefType "journal-article" @default.
- W1967564564 hasAuthorship W1967564564A5018869923 @default.
- W1967564564 hasAuthorship W1967564564A5023481360 @default.
- W1967564564 hasConcept C113196181 @default.
- W1967564564 hasConcept C124614425 @default.
- W1967564564 hasConcept C147789679 @default.
- W1967564564 hasConcept C17525397 @default.
- W1967564564 hasConcept C178790620 @default.
- W1967564564 hasConcept C179104552 @default.
- W1967564564 hasConcept C184651966 @default.
- W1967564564 hasConcept C185592680 @default.
- W1967564564 hasConcept C2779603750 @default.
- W1967564564 hasConcept C2779851234 @default.
- W1967564564 hasConcept C43617362 @default.
- W1967564564 hasConcept C52859227 @default.
- W1967564564 hasConcept C544778455 @default.
- W1967564564 hasConcept C68801617 @default.
- W1967564564 hasConcept C69118416 @default.
- W1967564564 hasConcept C88380143 @default.
- W1967564564 hasConcept C99541287 @default.
- W1967564564 hasConceptScore W1967564564C113196181 @default.
- W1967564564 hasConceptScore W1967564564C124614425 @default.
- W1967564564 hasConceptScore W1967564564C147789679 @default.
- W1967564564 hasConceptScore W1967564564C17525397 @default.
- W1967564564 hasConceptScore W1967564564C178790620 @default.
- W1967564564 hasConceptScore W1967564564C179104552 @default.
- W1967564564 hasConceptScore W1967564564C184651966 @default.
- W1967564564 hasConceptScore W1967564564C185592680 @default.
- W1967564564 hasConceptScore W1967564564C2779603750 @default.
- W1967564564 hasConceptScore W1967564564C2779851234 @default.
- W1967564564 hasConceptScore W1967564564C43617362 @default.
- W1967564564 hasConceptScore W1967564564C52859227 @default.
- W1967564564 hasConceptScore W1967564564C544778455 @default.
- W1967564564 hasConceptScore W1967564564C68801617 @default.
- W1967564564 hasConceptScore W1967564564C69118416 @default.
- W1967564564 hasConceptScore W1967564564C88380143 @default.
- W1967564564 hasConceptScore W1967564564C99541287 @default.
- W1967564564 hasIssue "1-2" @default.
- W1967564564 hasLocation W19675645641 @default.
- W1967564564 hasOpenAccess W1967564564 @default.
- W1967564564 hasPrimaryLocation W19675645641 @default.
- W1967564564 hasRelatedWork W16334835 @default.
- W1967564564 hasRelatedWork W1970696474 @default.
- W1967564564 hasRelatedWork W2063807660 @default.
- W1967564564 hasRelatedWork W2072730489 @default.
- W1967564564 hasRelatedWork W2166546637 @default.
- W1967564564 hasRelatedWork W2221461001 @default.
- W1967564564 hasRelatedWork W2354939568 @default.
- W1967564564 hasRelatedWork W2507360173 @default.
- W1967564564 hasRelatedWork W1586089731 @default.
- W1967564564 hasRelatedWork W199323151 @default.
- W1967564564 hasVolume "629" @default.
- W1967564564 isParatext "false" @default.
- W1967564564 isRetracted "false" @default.
- W1967564564 magId "1967564564" @default.
- W1967564564 workType "article" @default.