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- W1967573058 abstract "Ionic polymer prepared from acid–base interaction between methanesulfonic acid (MSA) and poly(4-vinylpyridine) (P4VP) or poly(styrene-co-4-vinylpyridine) (PS-P4VP) was served as dispersant for the emulsion polymerization of aniline. Dependent on the dispersants (as P4VP(MSA) or PS-P4VP(MSA)) used, the maximum amounts of polyaniline incorporated without premature precipitation during polymerization are different. A 3 wt.% of aniline in relative to P4VP(MSA) dispersant resulted in precipitation during polymerization; however, the aniline/PS-P4VP(MSA) ratio can reach 10 wt.% without the undesired precipitation if PS-P4VP(MSA) was used as dispersant. The inner PS block in PS-P4VP(MSA) can serve as a stabilizer to prevent the expansion of the outer P4VP(MSA) block and provided a more stable micelle system as compared with the aniline/P4VP(MSA) system. Spherical particles of different sizes were observed in products of low polyaniline contents (<3 wt.%). With increasing polyaniline contents, the conductive polyaniline phases tended to aggregated and separated from the dispersant matrix." @default.
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- W1967573058 date "2001-09-01" @default.
- W1967573058 modified "2023-10-16" @default.
- W1967573058 title "Emulsion polymerization of aniline with ionic dispersants containing ionic poly(vinylpyridinium methanesulfonate) segments" @default.
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- W1967573058 doi "https://doi.org/10.1016/s0379-6779(01)00350-2" @default.
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