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• W1967585247 abstract "A number of new N-heterocyclic carbene (NHC) ligands were synthesized via a multicomponent reaction, wherein an aldehyde or ketone, a primary amine and an α-acidic isocyanide were reacted, giving the corresponding 2H-2-imidazolines. These were easily alkylated with an alkyl halide at position N-3, yielding the final NHC precursors, that were then complexed with Ru in situ. The resulting complexes are shown to be active and selective catalysts for the transfer hydrogenation of furfural to furfurol, using isopropanol as the hydrogen source. Importantly, the carbene ligand remains coordinated to the ruthenium center throughout the reaction. Copyright © 2009 John Wiley & Sons, Ltd." @default.
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• W1967585247 date "2009-01-01" @default.
• W1967585247 modified "2023-10-11" @default.
• W1967585247 title "A facile route to ruthenium–carbene complexes and their application in furfural hydrogenation" @default.
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• W1967585247 doi "https://doi.org/10.1002/aoc.1584" @default.
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