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- W1967592021 abstract "Abstract We have built a 36-pixel high-resolution superconducting tunnel junction (STJ) soft X-ray spectrometer for chemical analysis of dilute metals by fluorescence-detected X-ray absorption spectroscopy (XAS) at the Advanced Light Source synchrotron. Soft X-ray absorption edges are preferred over traditional hard X-ray spectroscopy at the K-edges, since they have narrower natural linewidths and exhibit stronger chemical shifts. STJ detectors are preferred in the soft X-ray band over traditional Ge or grating spectrometers, since they have sufficient energy resolution to resolve transition metal L and M lines from light element K emission, and sufficient detection efficiency to measure the weak lines of dilute specimens within an acceptable time. We demonstrate the capabilities of our STJ spectrometer for chemical analysis with soft XAS measurements of molybdenum speciation on the Mo M 4,5 -edges." @default.
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- W1967592021 date "2006-04-01" @default.
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- W1967592021 title "The advantages of soft X-rays and cryogenic spectrometers for measuring chemical speciation by X-ray spectroscopy" @default.
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- W1967592021 doi "https://doi.org/10.1016/j.nima.2005.12.119" @default.
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