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- W1967598462 abstract "The room temperature dielectric permittivity of [100] oriented 0.37BiScO 3 -0.63PbTiO 3 (BSPT63) crystals with a morphotropic phase boundary (MPB) composition was found to be 1400, lower than that of BSPT57 crystals with rhombohedral phase (∼3000), but much higher than that of the tetragonal crystal BSPT66 (∼200). The Curie temperature of BSPT63 single crystals along [100] was found to be about 443°C, while the values were around 440°C and 445°C for [110] and [111] oriented crystals, respectively. Evidence of a ferroelectric–ferroelectric phase transformation temperature was associated with a dielectric anomaly occurring around 310–350°C for different orientations, indicating a strong curvature of the MPB. The coercive fields ( E c ) were found to be 20 kV/cm for [100] oriented crystals, 24 kV/cm and 27 kV/cm for [110] and [111] directions, respectively. The piezoelectric response for [100] oriented samples ( d 33 = 900 pC/N) is weaker than that in rhombohedral phase ( d 33 = 1200 pC/N) but much higher than that in tetragonal phase ( d 33 = 200 pC/N). The strain piezoelectric d 33 improved with the temperature increasing owing to dielectric permittivity increment, while the voltage piezoelectric g 33 is independent of temperature ( g 33 ∼0.074 m 2 /C). Evidence of a monoclinic phase for BSPT63 crystals is inferred using the X-ray powder diffraction (XRD), and the lattice parameters were calculated to be a =4.0751 Å, b =3.9765 Å, c =3.9893 Å and β=90.166°." @default.
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- W1967598462 date "2004-09-01" @default.
- W1967598462 modified "2023-10-14" @default.
- W1967598462 title "Dielectric and Piezoelectric Properties of BiScO<sub>3</sub>-PbTiO<sub>3</sub> Crystals with Morphotropic Phase Boundary Composition" @default.
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- W1967598462 doi "https://doi.org/10.1143/jjap.43.6199" @default.
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