FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1967641104> ?p ?o ?g. }

• W1967641104 endingPage "23" @default.
• W1967641104 startingPage "12" @default.
• W1967641104 abstract "The kinetics and mechanism of graphite gasification by CO2 and H2O catalyzed by five alkali and alkaline earth metal catalysts are investigated by studying the monolayer channeling action on the basal plane of graphite. CO2 and H2O are dissociatively chemisorbed by these catalysts, followed by diffusion of O atoms/ions to the edge carbon sites, where breakage of C&.sbnd;C bonds takes place to free CO. The CC bond breakage is the rate-limiting step. The catalytic activities as measured by the turnover frequencies on the edge carbon sites follow the order K > Ba > Ca > Na > Li. The same catalytic mechanism and rate-limiting step operate in both channeling action and bulk reactions using mixed powders of carbon and catalysts. The results on channeling also indicate that the active intermediates are catalysts in the form of particles and clusters, and that the C&.sbnd;OM (where M denotes metal) phenolate groups, although present in abundant amounts, are not the active intermediates. For very small particles, the surface free energy appears to play a role in lowering the amounts of CO2 and H2O chemisorbed, hence decreasing the channeling rates." @default.
• W1967641104 created "2016-06-24" @default.
• W1967641104 creator A5039136253 @default.
• W1967641104 date "1992-11-01" @default.
• W1967641104 modified "2023-10-12" @default.
• W1967641104 title "Mechanism of alkali and alkaline earth catalyzed gasification of graphite by CO2 and H2O studied by electron microscopy" @default.
• W1967641104 cites W1506690655 @default.
• W1967641104 cites W1560428456 @default.
• W1967641104 cites W1968266881 @default.
• W1967641104 cites W1975152970 @default.
• W1967641104 cites W1975271169 @default.
• W1967641104 cites W1975971500 @default.
• W1967641104 cites W1984278550 @default.
• W1967641104 cites W1988868182 @default.
• W1967641104 cites W1999305327 @default.
• W1967641104 cites W2000165175 @default.
• W1967641104 cites W2000717057 @default.
• W1967641104 cites W2001539684 @default.
• W1967641104 cites W2004447470 @default.
• W1967641104 cites W2005722017 @default.
• W1967641104 cites W2007844761 @default.
• W1967641104 cites W2009430584 @default.
• W1967641104 cites W2013598050 @default.
• W1967641104 cites W2017768339 @default.
• W1967641104 cites W2021100282 @default.
• W1967641104 cites W2022026658 @default.
• W1967641104 cites W2023151338 @default.
• W1967641104 cites W2026674148 @default.
• W1967641104 cites W2029396898 @default.
• W1967641104 cites W2029701583 @default.
• W1967641104 cites W2033306909 @default.
• W1967641104 cites W2037180213 @default.
• W1967641104 cites W2037735890 @default.
• W1967641104 cites W2039196198 @default.
• W1967641104 cites W2042366467 @default.
• W1967641104 cites W2043183201 @default.
• W1967641104 cites W2044840948 @default.
• W1967641104 cites W2062070676 @default.
• W1967641104 cites W2064726161 @default.
• W1967641104 cites W2065735134 @default.
• W1967641104 cites W2066662505 @default.
• W1967641104 cites W2069330667 @default.
• W1967641104 cites W2074708500 @default.
• W1967641104 cites W2078009033 @default.
• W1967641104 cites W2085999988 @default.
• W1967641104 cites W2086265042 @default.
• W1967641104 cites W2086438232 @default.
• W1967641104 cites W2091976270 @default.
• W1967641104 cites W2094351931 @default.
• W1967641104 cites W2094591427 @default.
• W1967641104 cites W2326332654 @default.
• W1967641104 cites W2342899681 @default.
• W1967641104 doi "https://doi.org/10.1016/0021-9517(92)90003-z" @default.
• W1967641104 hasPublicationYear "1992" @default.
• W1967641104 type Work @default.
• W1967641104 sameAs 1967641104 @default.
• W1967641104 citedByCount "81" @default.
• W1967641104 countsByYear W19676411042012 @default.
• W1967641104 countsByYear W19676411042013 @default.
• W1967641104 countsByYear W19676411042014 @default.
• W1967641104 countsByYear W19676411042015 @default.
• W1967641104 countsByYear W19676411042016 @default.
• W1967641104 countsByYear W19676411042017 @default.
• W1967641104 countsByYear W19676411042018 @default.
• W1967641104 countsByYear W19676411042019 @default.
• W1967641104 countsByYear W19676411042020 @default.
• W1967641104 countsByYear W19676411042021 @default.
• W1967641104 countsByYear W19676411042022 @default.
• W1967641104 countsByYear W19676411042023 @default.
• W1967641104 crossrefType "journal-article" @default.
• W1967641104 hasAuthorship W1967641104A5039136253 @default.
• W1967641104 hasConcept C104779481 @default.
• W1967641104 hasConcept C140205800 @default.
• W1967641104 hasConcept C159985019 @default.
• W1967641104 hasConcept C161790260 @default.
• W1967641104 hasConcept C178790620 @default.
• W1967641104 hasConcept C179104552 @default.
• W1967641104 hasConcept C185592680 @default.
• W1967641104 hasConcept C190463131 @default.
• W1967641104 hasConcept C192562407 @default.
• W1967641104 hasConcept C198091228 @default.
• W1967641104 hasConcept C2779015675 @default.
• W1967641104 hasConcept C2779698641 @default.
• W1967641104 hasConcept C62715864 @default.
• W1967641104 hasConceptScore W1967641104C104779481 @default.
• W1967641104 hasConceptScore W1967641104C140205800 @default.
• W1967641104 hasConceptScore W1967641104C159985019 @default.
• W1967641104 hasConceptScore W1967641104C161790260 @default.
• W1967641104 hasConceptScore W1967641104C178790620 @default.
• W1967641104 hasConceptScore W1967641104C179104552 @default.
• W1967641104 hasConceptScore W1967641104C185592680 @default.
• W1967641104 hasConceptScore W1967641104C190463131 @default.
• W1967641104 hasConceptScore W1967641104C192562407 @default.
• W1967641104 hasConceptScore W1967641104C198091228 @default.
• W1967641104 hasConceptScore W1967641104C2779015675 @default.
• W1967641104 hasConceptScore W1967641104C2779698641 @default.
• W1967641104 hasConceptScore W1967641104C62715864 @default.
• W1967641104 hasIssue "1" @default.

• next