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- W1967652855 abstract "Abstract We report spectroscopic constants of the jet-cooled 2-chloro-5-fluorobenzyl radical which was generated by corona discharge of precursor 2-chloro-5-fluorotoluene seeded in a large amount of helium carrier gas using a pinhole-type glass nozzle. The visible vibronic emission spectrum was recorded with a long-path monochromator. From an analysis of the spectrum observed, the electronic energy of the D 1 → D 0 transition and vibrational mode frequencies in the D 0 state were determined for the first time by comparing its vibronic data with those of a precursor and ab initio calculation. In addition, the substituent effect on electronic transition energy has been discussed." @default.
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- W1967652855 date "2014-09-01" @default.
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- W1967652855 title "Vibronic spectrum of jet-cooled 2-chloro-5-fluorobenzyl radical: Assignments and substituent effect" @default.
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- W1967652855 doi "https://doi.org/10.1016/j.cplett.2014.08.023" @default.
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