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- W1967658002 abstract "Uncatalysed Diels–Alder reactions between 1-(trimethylsiloxy)- or 1-acetoxy-buta-1,3-diene and sugar-derived nitroalkenes having D-galacto or D-manno configurations proceeded with complete regioselectivity. Diastereofacial specificity was also complete with the D-galacto dienophile, whereas it was only moderate with the D-manno. With 1-acetoxybuta-1,3-diene, interaction between reactants took place exclusively in the endo mode. Starting from cycloadducts, a series of highly functionalised chiral compounds have been prepared, their conformations and stereochemistries being investigated." @default.
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- W1967658002 date "1995-01-01" @default.
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- W1967658002 title "Asymmetric Diels–Alder reactions between chiral sugar nitroalkenes and 1-O-substituted buta-1,3-dienes. Synthesis and reactivity of new cyclohexenyl derivatives" @default.
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- W1967658002 doi "https://doi.org/10.1039/p19950001863" @default.
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