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• W1967674296 endingPage "6808" @default.
• W1967674296 startingPage "6808" @default.
• W1967674296 abstract "A study is reported on the relative stability of trivalent bis(ligand) complexes of the form [M(LR)2N′′] for trivalent group 3, lanthanide and actinide cations, using the sterically demanding N-heterocyclic carbene ligand LR = [OCMe2CH2{CNCH2CH2NR}] (R = iPr LP, Mes LM, Dipp LD; N′′ = N(SiMe3)2). For the small YIII cation (r6-coord = 1.040 Å) and the smallest LR, R = iPr, mono, bis, and tris(LP) complexes can be made; [Y(LP)2N′′] and [Y(LP)3] have been characterised. For the larger ligands, LM and LD, only the mono(LR) complexes [Y(LM)N′′2] and [Y(LD)N′′2] can be made. For the larger CeIII (r6-coord = 1.15 Å), mono(LR) and bis(LR) complexes [Ce(LM)N′′2], [Ce(LD)N′′2], [Ce(LM)2N′′], and [Ce(LD)2N′′] can be made; structural characterisation of the latter two confirm the high degree of steric congestion. The new complex [U(LM)N′′2] has also been isolated. Despite the very similar radii of CeIII and UIII (r6-coord = 1.165 Å), the complexes [U(LR)2N′′] cannot be isolated; a surprising display of the difference between the 4f and 5f metal series. However, the six-coordinate, bis(ligand) UIV complexes can readily be isolated if smaller ancillary ligands are used; [U(LM)2I2] and [U(LD)2I2] have been fully, including structurally, characterised." @default.
• W1967674296 created "2016-06-24" @default.
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• W1967674296 date "2010-01-01" @default.
• W1967674296 modified "2023-10-16" @default.
• W1967674296 title "Lanthanide/actinide differentiation with sterically encumbered N-heterocyclic carbene ligands" @default.
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• W1967674296 doi "https://doi.org/10.1039/c001584a" @default.
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