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• W1967683966 abstract "A series of fluorescent pH probes based on the spiro-cyclic rhodamine core, aminomethylrhodamines (AMR), was synthesized and the effect of cycloalkane ring size on the acid/base properties of the AMR system was explored. The study involved a series of rhodamine 6G (cAMR6G) and rhodamine B (cAMR) pH probes with cycloalkane ring sizes from C-3 to C-6 on the spiro-cyclic amino group. It is known that the pKa value of cycloalkylamines can be tuned by different ring sizes in accordance with the Baeyer ring strain theory. Smaller ring amines have lower pKa value, i.e., they are less basic, such that the relative order in cycloalkylamine basicity is: cyclohexyl > cyclopentyl > cyclobutyl > cyclopropyl. Herein, it was found that the pKa values of the cAMR and cAMR6G systems can also be predicted by Baeyer ring strain theory. The pKa values for the cAMR6G series were shown to be higher than the cAMR series by a value of approximately 1." @default.
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• W1967683966 date "2015-02-17" @default.
• W1967683966 modified "2023-09-26" @default.
• W1967683966 title "Cycloalkyl-AminoMethylRhodamines: pH Dependent Photophysical Properties Tuned by Cycloalkane Ring Size" @default.
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• W1967683966 doi "https://doi.org/10.1007/s10895-015-1519-z" @default.
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