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- W1967726205 abstract "The external chiral ligand-induced enantioselective [2,3]-Wittig rearrangements of crotyl benzyl ethers and crotyl propargylic ethers are described. The most notable is that treatment of (E)-crotyl propargylic ethers with a t-butyllithium/(S;S)-bis(oxazoline) complex provides a relatively high enantioselectivity (up to 89% ee), together with a high threo-diastereoselectivity. Furthermore, examples of the “asymmetric catalytic version” of the rearrangement of crotyl benzyl ethers are presented. Chirality 12:505–509, 2000. © 2000 Wiley-Liss, Inc." @default.
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- W1967726205 date "2000-01-01" @default.
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- W1967726205 title "External chiral ligand-induced enantioselective versions of the [2,3]-Wittig sigmatropic rearrangement" @default.
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- W1967726205 doi "https://doi.org/10.1002/(sici)1520-636x(2000)12:5/6<505::aid-chir36>3.0.co;2-3" @default.
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