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- W1967754719 abstract "A novel route to enolates from silyl enol ethers and enol acetates has been studied and optimized. A range of lithium, sodium and, particularly, potassium enolates were quantitatively prepared under very simple conditions. This new methodology involved an alkoxide-mediated reaction to form enolates, which were subjected to regiospecific alkylation, aldolisation, or Michael reaction. In some cases, only a catalytic amount of alkali metal alkoxides was needed. A new prenylation method, leading to polyene aldehydes belonging to the vitamin A series, has also been described. Finally, a new concept based on retroaldol reaction has been applied to asymmetric synthesis." @default.
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- W1967754719 date "2001-03-01" @default.
- W1967754719 modified "2023-10-12" @default.
- W1967754719 title "Alkoxide-Mediated Preparation of Enolates from Silyl Enol Ethers and Enol Acetates − From Discovery to Synthetic Applications" @default.
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