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- W1967776952 abstract "Abstract Nanocrystalline Mg–Ni alloy powder was produced via the magnetron co-sputtering technique. The samples obtained showed crystallisation of Mg and Mg 2 Ni and an overall morphological heterogeneity with different enriched zones, as evidenced by microstructural analysis. A number of pressure-composition-isotherms (PCI) were carried out on these samples at a range of temperatures. Following hydrogenation, different hydrogen sorption behaviours were observed depending on the samples’ relative composition in terms of Mg and Mg 2 Ni. Hydrogenation/dehydrogenation cycling is believed to have caused modification of the nanocrystalline materials investigated. The derived dissociation enthalpies of the corresponding hydrides, MgH 2 and Mg 2 NiH 4 , were found to be coherent with values reported in literature, with the exception of two samples. In addition, one of these samples showed a third plateau pressure pointing to the presence of a hydrogenated metastable phase." @default.
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- W1967776952 date "2008-06-01" @default.
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- W1967776952 title "Exploring the hydrogen sorption capacity of Mg–Ni powders produced by the vapour deposition technique" @default.
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- W1967776952 doi "https://doi.org/10.1016/j.ijhydene.2008.02.011" @default.
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