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- W1967828045 abstract "EDTA and other aminopolycarboxylic acids increase the rate of reduction of chromium (VI) by hydrazine. After the reduction, part of the chromium(III) is present as the aminopolycarboxylato complex although such complexes form very slowly under the same experimental conditions from chromium(III) and the ligand. The experimental finding, that the amount of chromium(VI) converted to chromium(III)-EDTA complex reaches a limiting value of one half of the total chromium with increasing concentration of EDTA, is explained. A mechanism is put forward involving the assumption of the formation of very stable chromium(VI)-EDTA-hydrazine mixed complexes. The effects of different aminopolycarboxylic acids on the mechanims of the reduction of chromium(VI) are not identical." @default.
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- W1967828045 date "1971-02-01" @default.
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- W1967828045 title "The effect of EDTA on the hydrazine-chromium(VI) reaction" @default.
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- W1967828045 doi "https://doi.org/10.1016/0022-1902(71)80389-5" @default.
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