FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1967868049> ?p ?o ?g. }

• W1967868049 endingPage "6107" @default.
• W1967868049 startingPage "6101" @default.
• W1967868049 abstract "The synthesis of the novel tripodal ligand [N(CH2CH2CH2OH)(CH2CH2SH)2] H3-4 is reported. The aliphatic tetradentate ligand is equipped with an unsymmetrical NOS2 donor set. It reacts with Ni(OAc)2·4H2O or Zn(BF4)2·xH2O to give the complexes [Ni(H-4)]2 5 and [Zn(H-4)]4 6, respectively. The molecular structures of 5 and 6 have been determined by X-ray diffraction. In both cases multinuclear, μ-thiolato-bridged complexes, wherein the ligand coordinates with only three (NS2) of the four donor groups, had formed. The dinuclear complex 5 adopts a butterfly geometry and contains nickel(II) ions in a square-planar NS3 coordination environment. Cyclic voltammetry experiments indicate that the nickel centers in 5 are electron-rich but not overly sensitive toward oxidation. Complex 6 is tetranuclear and the four thiolato-bridged metal centers form a ring. It shows a distorted tetrahedral coordination geometry for the zinc(II) ions in an NS3 coordination sphere. In both complexes the hydroxyl functionalized ligand arm of the tripodal ligand remains uncoordinated." @default.
• W1967868049 created "2016-06-24" @default.
• W1967868049 creator A5019474679 @default.
• W1967868049 creator A5039921470 @default.
• W1967868049 creator A5057906823 @default.
• W1967868049 creator A5081280594 @default.
• W1967868049 date "2004-08-25" @default.
• W1967868049 modified "2023-10-17" @default.
• W1967868049 title "An Unsymmetrical Tripodal Ligand with NOS₂-Donor Set: Coordination Chemistry with Nickel(II) and Zinc(II)" @default.
• W1967868049 cites W1965545487 @default.
• W1967868049 cites W1968768423 @default.
• W1967868049 cites W1971509230 @default.
• W1967868049 cites W1975165348 @default.
• W1967868049 cites W1979547107 @default.
• W1967868049 cites W1980553579 @default.
• W1967868049 cites W1981125958 @default.
• W1967868049 cites W1983056223 @default.
• W1967868049 cites W1985228640 @default.
• W1967868049 cites W1985572160 @default.
• W1967868049 cites W1988656249 @default.
• W1967868049 cites W1992206711 @default.
• W1967868049 cites W1993637922 @default.
• W1967868049 cites W1994335443 @default.
• W1967868049 cites W1994743549 @default.
• W1967868049 cites W1997333914 @default.
• W1967868049 cites W1999315517 @default.
• W1967868049 cites W2000090924 @default.
• W1967868049 cites W2002783776 @default.
• W1967868049 cites W2004031437 @default.
• W1967868049 cites W2005098392 @default.
• W1967868049 cites W2008143822 @default.
• W1967868049 cites W2011093366 @default.
• W1967868049 cites W2012322123 @default.
• W1967868049 cites W2016614838 @default.
• W1967868049 cites W2016656463 @default.
• W1967868049 cites W2021887274 @default.
• W1967868049 cites W2022350441 @default.
• W1967868049 cites W2022391117 @default.
• W1967868049 cites W2023252389 @default.
• W1967868049 cites W2026427334 @default.
• W1967868049 cites W2028319725 @default.
• W1967868049 cites W2028343307 @default.
• W1967868049 cites W2029353465 @default.
• W1967868049 cites W2033076771 @default.
• W1967868049 cites W2034846786 @default.
• W1967868049 cites W2039487308 @default.
• W1967868049 cites W2043017675 @default.
• W1967868049 cites W2043367467 @default.
• W1967868049 cites W2043888901 @default.
• W1967868049 cites W2048961993 @default.
• W1967868049 cites W2053797172 @default.
• W1967868049 cites W2055266280 @default.
• W1967868049 cites W2058201918 @default.
• W1967868049 cites W2065237372 @default.
• W1967868049 cites W2067416688 @default.
• W1967868049 cites W2073264677 @default.
• W1967868049 cites W2080891525 @default.
• W1967868049 cites W2082644742 @default.
• W1967868049 cites W2086229198 @default.
• W1967868049 cites W2089823615 @default.
• W1967868049 cites W2090252042 @default.
• W1967868049 cites W2131631516 @default.
• W1967868049 cites W2144027499 @default.
• W1967868049 cites W2148062424 @default.
• W1967868049 cites W2148066840 @default.
• W1967868049 cites W2155877380 @default.
• W1967868049 cites W2312205404 @default.
• W1967868049 cites W2314585142 @default.
• W1967868049 cites W2512910035 @default.
• W1967868049 doi "https://doi.org/10.1021/ic0491940" @default.
• W1967868049 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15360262" @default.
• W1967868049 hasPublicationYear "2004" @default.
• W1967868049 type Work @default.
• W1967868049 sameAs 1967868049 @default.
• W1967868049 citedByCount "20" @default.
• W1967868049 countsByYear W19678680492012 @default.
• W1967868049 countsByYear W19678680492013 @default.
• W1967868049 countsByYear W19678680492014 @default.
• W1967868049 countsByYear W19678680492017 @default.
• W1967868049 countsByYear W19678680492023 @default.
• W1967868049 crossrefType "journal-article" @default.
• W1967868049 hasAuthorship W1967868049A5019474679 @default.
• W1967868049 hasAuthorship W1967868049A5039921470 @default.
• W1967868049 hasAuthorship W1967868049A5057906823 @default.
• W1967868049 hasAuthorship W1967868049A5081280594 @default.
• W1967868049 hasConcept C11111787 @default.
• W1967868049 hasConcept C112887158 @default.
• W1967868049 hasConcept C115624301 @default.
• W1967868049 hasConcept C116569031 @default.
• W1967868049 hasConcept C170493617 @default.
• W1967868049 hasConcept C178790620 @default.
• W1967868049 hasConcept C185592680 @default.
• W1967868049 hasConcept C194196696 @default.
• W1967868049 hasConcept C2779868791 @default.
• W1967868049 hasConcept C32909587 @default.
• W1967868049 hasConcept C504270822 @default.
• W1967868049 hasConcept C535196362 @default.
• W1967868049 hasConcept C544153396 @default.

• next