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- W1967873107 abstract "Electron scattering on small negatively charged polyatomic molecules has been studied at the heavy-ion storage ring ASTRID. O3−, NO3− and SO2− ions were merged with a cold electron beam, and the relative reaction cross sections were measured for collision energies in the range from 0 to about 50 eV. The absolute magnitudes of the cross sections are predicted using a classical reaction model, and we compare all previously published detachment thresholds from storage ring experiments to the electron affinities of the corresponding atomic and molecular species. A classical over-the-barrier model predicts the atomic anion thresholds well, whereas Franck–Condon factors play a role for molecular ions. Moreover, branching ratios for molecular break-up into different final channels were determined." @default.
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- W1967873107 date "2003-01-01" @default.
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- W1967873107 title "Electron-impact detachment of O<sub>3</sub><sup>−</sup>, NO<sub>3</sub><sup>−</sup>and SO<sub>2</sub><sup>−</sup>ions" @default.
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- W1967873107 doi "https://doi.org/10.1039/b309322k" @default.
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