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- W1967891664 abstract "The change of spectroscopic properties of sodium-water and sodium-ammonia complexes upon deuteration is investigated. The ionization potential of NaD2O is shifted by 70 cm−1 towards lower energies compared to NaH2O. A shift of 81 cm−1 between NaND3 and NaNH3 is observed again towards lower energies. From these shift the vibrational frequencies for the ground state of the neutral and ionic complex have been estimated. The first electronically excited state (Ã2E) of NaND3 has been investigated by resonant two color two photon ionization. The comparison with the formerly observed NaNH3 spectrum enables us to do an unequivocal assignment of the vibrational structure." @default.
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- W1967891664 date "1997-12-15" @default.
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- W1967891664 title "Electronically excited states in size selected solvated alkali metal atoms. II. Isotope effects in the spectroscopy of sodium water and sodium ammonia complexes" @default.
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- W1967891664 doi "https://doi.org/10.1063/1.475277" @default.
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