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- W1967894017 abstract "Abstract A copper catalyst bearing a suitable Xantphos derivative or NHC ligand was found to be highly efficient for the selective semihydrogenation of non‐polar unsaturated compounds using a mixture of a silane and an alcohol as reducing agent. The catalytic system was useful for the selective semihydrogenation of internal alkynes to ( Z )‐alkenes with suppression of overreduction to the corresponding alkanes. Furthermore, semihydrogenations of terminal alkyne, 1,2‐diene, 1,3‐diene, 1,3‐enyne and 1,3‐diyne systems were also achieved selectively." @default.
- W1967894017 created "2016-06-24" @default.
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- W1967894017 date "2012-05-15" @default.
- W1967894017 modified "2023-10-18" @default.
- W1967894017 title "Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol" @default.
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- W1967894017 doi "https://doi.org/10.1002/adsc.201200200" @default.
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