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- W1967900571 abstract "Abstract The deposition of floating monolayers onto solid substrates to give Langmuir—Blodgett (LB) multilayers requires that the precursor monolayers should be stable to loss, either by collapse or dissolution, over the deposition interval. Only little work on monolayer stability has been reported previously and then usually for straight-chain alkanoic acids. In the present paper we report on monolayer stabilities of a range of novel potential LB materials. The hydrophobic chain structures have been methodically modified and various isomers and homologues have been studied. Alkylphenyl and alkoxyphenyl chains as well as chains containing biphenyl groups and double bonds have been included in the investigation. In addition to the COOH head group, which is sensitive to pH, we have also considered materials with CN and CH 2 OH head groups which are not pH sensitive. We also report results obtained for monolayers of cholesterol, cholestanol and cholestanyl nitrile." @default.
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- W1967900571 date "1992-07-01" @default.
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- W1967900571 title "Effects of molecular structure on the stability of insoluble monolayers" @default.
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- W1967900571 doi "https://doi.org/10.1016/0166-6622(92)80172-x" @default.
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