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- W1967945963 abstract "The reactions of [W(η-C5H5)2H2](1) with carboxylic acids under various conditions were investigated. At room temperature in the dark, the reaction afforded reversibly [W(η-C5H5)2H3]+(3), whereas the same reaction under irradiation by light yielded [W(η-C5H5)2(OCOR)2](2)[R = Me, Et, CH2C(Me), or H] in small amounts. Addition of 1 equivalent of O2 to the reaction system significantly improved the yields of (2) producing water as a by-product. Complexes (2) containing unidentate carboxylate were characterised by i.r. and 1H n.m.r. spectra and by elemental analyses. The formation of the species [W(η-C5H5)2(OCOMe)(H2O)]+ was proposed on the basis of the 1H n.m.r. measurements of (2; R = Me) in CD3CO2D containing D2O." @default.
- W1967945963 created "2016-06-24" @default.
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- W1967945963 date "1987-01-01" @default.
- W1967945963 modified "2023-10-11" @default.
- W1967945963 title "Preparation and characterisation of dicarboxylatobis(η-cyclopentadienyl)-tungsten(<scp>IV</scp>) complexes: a novel and convenient synthesis from [W(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>H<sub>2</sub>] using molecular oxygen as a hydrogen acceptor" @default.
- W1967945963 doi "https://doi.org/10.1039/dt9870001857" @default.
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