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• W1967948468 abstract "In this work, hematite tire-like single crystals were fabricated by a facile hydrothermal procedure. The presence of NH4+ cations in the reaction was proved to be decisive to the formation of hematite single-crystalline tires. It was found that the (001) crystallographic plane, doubly-coordinated by surface hydroxyl groups, preferably distributes at the edge of originally-formed oblate spheroids and dynamically adsorbs NH4+ cations in solution, which would greatly protect this plane from being etched by [Fe(HPO4)]+ and H+ cations during the reaction. Meanwhile, these remanent etch-proof nanoparticles would co-align, followed by the oriented attachment mechanism, and finally form tire-like single crystals enclosed by (001) surface. Even though these single-crystalline tires were bound by low-index facet, their photocatalytic properties were quite unique due to their high density of surface hydroxyl radicals." @default.
• W1967948468 created "2016-06-24" @default.
• W1967948468 creator A5029133149 @default.
• W1967948468 creator A5075279956 @default.
• W1967948468 date "2014-06-17" @default.
• W1967948468 modified "2023-09-27" @default.
• W1967948468 title "NH4+-mediated growth of hematite tire-like single crystals by oriented attachment and their unique photocatalytic properties" @default.
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• W1967948468 doi "https://doi.org/10.1088/2053-1591/1/2/025039" @default.
• W1967948468 hasPublicationYear "2014" @default.
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