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- W1967950731 abstract "The densities of dilute aqueous solutions of two homologous organic salts, RNH3Cl and RCOONa, where R varies from H to n-octyl, have been measured at 5, 25, and 45 °C using a buoyancy technique. The apparent molal volumes, φv, of the salts and the limiting partial molal volumes, barV°, of the individual ions have been evaluated. The contributions of a methylene group to the partial molal volume, barV°(CH2), as estimated from the barV° data for longer-chain salts, are nearly the same for both series: approximately 15.3, 15.9, and 16.5 ml/mol at 5, 25, and 45 °C respectively. Compared to these values, on the other hand, the barV°(CH2) estimated for shorterchain RNH3Cl is larger and that for shorter-chain RCOONa is smaller. The second derivative of the barV° with respect to the temperature, ∂2barV°⁄∂T2, which is often regarded as a useful measure of structural effects, is almost independent of the chain length for longer-chain homologues. The concentration dependence of φv does not always vary in a reg..." @default.
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- W1967950731 date "1975-12-01" @default.
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- W1967950731 title "Apparent Molal Volumes of<i>n</i>-Alkylammonium Chlorides and Sodium<i>n</i>-Alkanecarboxylates in Dilute Aqueous Solutions" @default.
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- W1967950731 doi "https://doi.org/10.1246/bcsj.48.3491" @default.
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